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Publications
33. Gitter, S. R., Teh, W. P., Yang, X., Dohoda, A. F., Michael, F. E., Boydston, A.J. "C−H Functionalization and Allylic Amination for Post-Polymerization Modification of Polynorbornenes" Angew. Chem. Int. Ed. 2023, e202303174
32. Hodges, M. N., Elardo, M. J., Seo, J., Dohoda, A.F., Michael, F. E., Golder, M. R. "Upcycling of Polybutadiene Facilitated by Selenium-Mediated Allylic Amination" Angew. Chem. Int. Ed. 2023, e202303115
31. Obenschain, D. C., Tabor, J. R., Michael, F. E. "Metal-Free Intermolecular Allylic C–H Amination of Alkenes Using Primary Carbamates" ACS Catalysis 2023, 13, 4369-4375
30. Maloney, T. P., Berman, J. L., Michael, F. E. "Metal-Free Allylic C−H Amination of Vinylsilanes and Vinylboronates using Silicon or Boron as a Regioselectivity Switch" Angew. Chem. Int. Ed. 2022, 61(45), e202210109. DOI: 10.1002/anie.202210109
29. Zheng, T.; Berman, J. L.; Michael, F. E. "Diastereoconvergent synthesis of anti-1,2-amino alcohols with N-containing quaternary stereocenters via selenium-catalyzed intermolecular C–H amination” Chem. Sci. 2022, Advance Article. DOI: 10.1039/C9SC05335B
28. Maloney, T. P.; Dohoda, A. F.; Zhu, A. C., Michael, F. E. "Stereoretentive and Regioselective Selenium-catalyzed Intermolecular Propargylic C-H Amination of Alkynes” Chem. Sci. 2022, 13, Accepted Manuscript DOI: 10.1039/D1SC07067C
27. Teh, W. P.; Obenschain, D. C.; Black, B. M., Michael, F. E. "Catalytic Metal-free Allylic C-H Amination of Terpenoids” J. Am. Chem. Soc. 2020, 142, 16717-16722. DOI: 10.1021/jacs.0c06997
26. Tabor, J. R.; Obenschain, D. C.; Michael, F. E. "Selenophosphoramide-Catalyzed Diamination and Oxyamination of Alkenes” Chem. Sci. 2020, 11, 1677-1682. DOI: 10.1039/C9SC05335B
25. Zheng, T.; Tabor, J. R.; Stein, Z. L.; Michael, F. E. “Regioselective Metal-Free Aza-Heck Reactions of Terminal Alkenes Catalyzed by Phosphine Selenides” Org. Lett. 2018, 20, 6975-6978. DOI: 10.1021/acs.orglett.8b03159
24. Teh, W. P.; Michael, F. E. “Palladium-Catalyzed Cross-Coupling of N-Sulfonylaziridines and Alkenylboronic Acids: Stereospecific Synthesis of Homoallylic Amines with Di-and Trisubstituted Alkenes” Org. Lett. 2017, 19, 1738-1740. DOI: 10.1021/acs.orglett.7b00504
23. Ingalls, E. L.; Holtzen, G. A.; Kaminsky, W.; Michael, F. E. “Synthesis and Structural Characterization of Palladium(II) Complexes of Chiral Bidentate N-Heterocyclic Carbene-Quinoline Ligands” J. Organomet. Chem. 2017, 832, 9-11. DOI: 10.1016/j.jorganchem.2017.01.008
22. Rosewall, C. F.; Ingalls, E. L.; Kaminsky, W.; Michael, F. E. “Chelation-driven Rearrangement of Primary Alkyl Aminopalladation Products to Stable Trisubstituted Alkyl Palladium Complexes” Angew. Chem. Int. Ed. 2015, 54, 4557-4560. DOI: 10.1002/anie.201412033
21. Duda, M. L.; Michael, F. E. “Palladium-Catalyzed Cross-Coupling of N-Sulfonylaziridines with Boronic Acids” J. Am. Chem. Soc. 2013, 135, 18347-18349. DOI: 10.1021/ja410686v
20. Pierson, J.; Ingalls, E. L.; Vo, R.; Michael, F. E. “Palladium(II)-Catalyzed Intramolecular Hydroamination of 1,3-Dienes to Give Homoallylic Amines” Angew. Chem. Int. Ed. 2013, 52, 13311-13313. DOI: 10.1002/anie.201305766
19. McGhee, A.; Cochran, B. M.; Stenmark, T.; Michael F. E. “Stereoselective synthesis of 2,5-disubstituted morpholines using a palladium-catalyzed hydroamination reaction” Chem. Comm. 2013, 49, 6800-6802. DOI: 10.1039/C3CC44117B
18. Ingalls, E. L.; Sibbald, P. A.; Kaminsky, W.; Michael, F. E. “Enantioselective Palladium-Catalyzed Diamination of Alkenes Using N-Fluorobenzenesulfonamide” J. Am. Chem. Soc. 2013, 135, 8854-8856. DOI: 10.1021/ja4043406
17. Okamoto, K.; Housekeeper, J. B.; Michael, F. E.; Luscombe, C. K. “Thiophene based hyperbranched polymers with tunable branching using direct arylation methods” Polym. Chem. 2013, 4, 3499-3506. DOI: 10.1039/C3PY00412K
16. Bjelic, S.; Nivon, L. G.; Celebi-Olcum, N.; Kiss, G.; Rosewall, C. F.; Lovick, H. M.; Ingalls, E. L.; Gallaher, J. L.; Seetharaman, J.; Lew, S.; Montelione, G. T.; Hunt, J. F.; Michael, F. E.; Houk, K. N.; Baker, D. “Computational Design of Enone-Binding Proteins with Catalytic Activity for the Morita-Baylis-Hillman Reaction” ACS Chemical Biology 2013, 8, 749-757. DOI: 10.1021/cb3006227
15. Liskin, D. V.; Sibbald, P. A.; Rosewall, C. F.; Michael, F. E. “Palladium Catalyzed Alkoxyamination of Alkenes with Use of N-Fluorobenzenesulfonimide as Oxidant.” J. Org. Chem. 2010, 75, 6294–6296. DOI: 10.1021/jo101171g
14. Siegel, J. B.; Zanghellini, A.; Lovick, H. M.; Kiss, G.; Lambert, A. R.; St.Clair, J. L.; Gallaher, J. L.; Hilvert, D.; Gelb, M. H.; Stoddard, B.; Houk, K. N.; Michael, F. E.; Baker, D. “Computational design of an enzyme catalyst for a stereoselective bimolecular Diels-Alder reaction.” Science 2010, 329, 309–313. DOI: 10.1126/science.1190239
13. Hoover, J. M.; DiPasquale, A.; Mayer, J. M.; Michael, F. E. “Platinum Catalyzed Intramolecular Hydrohydrazination: Evidence for Alkene Insertion into a Pt-N Bond.” J. Am. Chem. Soc. 2010, 132, 5043–5053. DOI: 10.1021/ja906563z
12. Lovick, H. M.; Michael, F. E. “Metal-Free Highly Regioselective Aminotrifluoroacetoxylation of Alkenes.” J. Am. Chem. Soc. 2010, 132, 1249–1251. DOI: 10.1021/ja906648w
11. Sibbald, P. A.; Rosewall, C. F.; Swartz, R. D.; Michael, F. E. “Mechanism of N-Fluorobenzenesulfonimide Promoted Diamination and Carboamination Reactions: Divergent Reactivity of a Pd(IV) Species.” J. Am. Chem. Soc. 2009, 131, 15945–15951. DOI: 10.1021/ja906915w
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10. Rosewall, C. F.; Sibbald, P. A.; Liskin, D. V.; Michael, F. E. “Palladium Catalyzed Carboamination of Alkenes Promoted by N-Fluorobenzenesulfonimide via C-H Activation of Arenes.” J. Am. Chem. Soc. 2009, 131, 9488–9489. DOI: 10.1021/ja9031659
9. Sibbald, P. A.; Michael, F. E. “Palladium-Catalyzed Diamination of Unactivated Alkenes Using N-fluorobenzenesulfonimide as a Source of Electrophilic Nitrogen.” Org. Lett. 2009, 11, 1147–1149. DOI: 10.1021/ol9000087
8. Lovick, H. M.; Michael F. E. “Reversal of enantioselectivity using tethered bisguanidine catalysts in the aza-Henry reaction.” Tetrahedron Lett. 2009, 50, 1016–1019. DOI: 10.1016/j.tetlet.2008.12.058
7. Cochran, B. M.; Michael, F. E. “Metal-free Oxidative Cyclization of Urea-Tethered Alkenes with Hypervalent Iodine.” Org. Lett. 2008, 10, 5039–5042. DOI: 10.1021/ol8022165
6. Hoover, J. M.; Freudenthal, J.; Michael, F. E.; Mayer, J. M. “Reactivity of low-valent Ir, Rh, and Pt complexes with di- and tetrasubstituted hydrazines.” Organometallics 2008, 27, 2238–2245. DOI: 10.1021/om701192s
5. Sibbald, P. A.; Cochran, B. M.; Michael, F. E. “Palladium-Catalyzed Intramolecular Chloroamination of Alkenes.” Org. Lett. 2008, 9, 793–796. DOI: 10.1021/ol702922c
4. Cochran, B. M.; Michael, F. E. “Synthesis of 2,6-Disubstituted Piperazines by a Diastereoselective Palladium-Catalyzed Hydroamination Reaction.” Org. Lett. 2008, 9, 329–332. DOI: 10.1021/ol702891p
3. Cochran, B. M.; Michael, F. E. “Mechanistic Studies of a Palladium Catalyzed Intramolecular Hydroamination of Unactivated Alkenes: Protonolysis of a Stable Palladium Alkyl Complex is the Turnover-limiting Step.” J. Am. Chem. Soc. 2008, 130, 2786–2792. DOI: 10.1021/ja0734997
2. Hoover, J. M.; DiPasquale, A.; Mayer, J. M.; Michael, F. E. “Synthesis and Reactivity of a RuIII bis(anilide) Dimer by Oxidative Addition of an N,N′-disubstituted Hydrazine.” Organometallics 2007, 26, 3397–3405. DOI: 10.1021/om0700462
1. Michael, F. E.; Cochran, B. M. “Room-Temperature Palladium-Catalyzed Intramolecular Hydroamination of Unactivated Alkenes.” J. Am. Chem. Soc. 2006, 128, 4246–4248. DOI: 10.1021/ja060126h
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